姓名：林锦鸿，副教授、博士生导师

邮箱：jlin@shu.edu.cn

研究领域：有机氟化学、过渡金属催化

教育经历：

2001/9-2005/7: 东华大学，学士

2005/9-2011/1：中科院上海有机化学研究所，有机化学，博士，导师：肖吉昌研究员

工作经历：

2011/3-2013/2：纽约州立大学Albany分校，博士后，导师：John T. Welch

2013/3-2021/4：中科院上海有机化学研究所，副研究员

2021/4-至今：古天乐代言太阳集团化学系，副教授，博士生导师

人才项目

2019年入选中科院青年创新促进会

主持科研项目：

(1) 国家自然科学基金面上项目，2023年1月至2026年12月，主持

(2) 上海市科学技术委员会自然科学基金面上项目，2022年04月至 2025年 03月，主持

(3) 国家自然科学基金青年科学基金项目，2016年01月至 2018年 12月，主持

(4) 上海市科学技术委员会自然科学基金项目，2014年07月至2017年06月，主持

代表性学术论文（第一作者或通讯作者文章，按时间倒序排列）：

(1) Wang, Z.; Lin, J.-H.;* Xiao, J.-C.* Photocatalytic Keto- and Amino-Trifluoromethylation of Alkenes. Org. Lett. 2024, 26, 1980–1984.

(2) Pan, W.-J.; Yu, J.; Cao, W.-G.;* Xiao, J.-C.*; Lin, J.-H.* Difluorocarbene as a C–F source for the construction of fluorinated benzothiazoles. Org. Chem. Front. 2024, 11, 120-126.

(3) Xiang, Y.-J.; Liu, S.; Zhou, J.; Lin, J.-H.;* Yao, X.;* Xiao, J.-C.* Dehydroxylative Sulfonylation of Alcohols. J. Org. Chem. 2023, 88, 4818-4828.

(4) Chen, L.-Y.; Pan, P.-F.; Lin, J.-H.;* Jin, C.-M.;* Xiao, J.-C.* Tf2O as a CF3 Source for the Synthesis of Trifluoromethoxylation Reagent nC4F9SO3CF3. J. Org. Chem. 2023, 88, 3346-3352.

(5) Zhang, F.-X.; Lin, J.-H.;* Xiao, J.-C.* Difluoromethylsulfonyl Imidazolium Salt for Difluoromethylation of Alkenes. Org. Lett. 2022, 24, 7611-7616.

(6) Zhou, W.; Pan, W.-J.; Chen, J.; Zhang, M.; Lin, J.-H.;* Cao, W.;* Xiao, J.-C.* Transition-metal difluorocarbene complexes. Chem. Commun. 2021, 57, 9316-9329.

(7) Yang, Y.-F.; Lin, J.-H.;* Xiao, J.-C.* Starting from Styrene: A Unified Protocol for Hydrotrifluoromethylation of Diversified Alkenes. Org. Lett. 2021, 23, 9277-9282.

(8) Hao, F.; Shang, X.; Liu, Z.; Zhang, H.;* Lin, J.-H.;* Xiao, J.-C.* Rh-catalyzed tunable defluorinative borylation. Chem. Commun. 2021, 57, 7124-7127.

(9) Zhang, W.; Gu, Y. C.; Lin, J.-H.;* Xiao, J.-C.* Dehydroxylative Fluorination of Tertiary Alcohols. Org. Lett. 2020, 22, 6642-6646.

(10) Xu, Z.-W.; Zhang, W.; Lin, J.-H.;* Jin, C. M.;* Xiao, J.-C.* Pd‐catalyzed transfer of difluorocarbene for three component cross‐coupling. Chin. J. Chem. 2020, 38, 1647－1650.

(11) Lin, J.-H.; Xiao, J.-C.* Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts. Acc. Chem. Res. 2020, 53, 1498-1510.

(12) Liu, Z.; Long, J.; Xiao, X.; Lin, J.-H.;* Zheng, X.;* Xiao, J.-C.*; Cao, Y.-C. Ph3P+CF2CO2- as an F- and :CF2 source for trifluoromethylthiolation of alkyl halides. Chin. Chem. Lett. 2019, 30, 714 - 716.

(13) Zhao, Y.; Lin, J.-H.;* Hang, X.-C.;* Xiao, J.-C.* Ag-Mediated Trifluoromethylthiolation of Inert Csp3–H Bond. J. Org. Chem. 2018, 83, 14120-14125.

(14) Pan, X.-Y.; Zhao, Y.; Qu, H.-A.; Lin, J.-H.;* Hang, X.-C.;* Xiao, J.-C.* Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis. Org. Chem. Front. 2018, 5, 1452-1456.

(15) Yu, J.; Lin, J.-H.;* Xiao, J.-C.* Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines. Angew. Chem. Int. Ed. 2017, 56, 16669-16673.

(16) Huang, Q.-X.; Zheng, Q.-T.; Duan, Y.; Lin, J.-H.;* Xiao, J.-C.*; Zheng, X.* Diastereoselective Synthesis of CF3-Containing Vicinal Diamines. J. Org. Chem. 2017, 82, 8273-8281.

(17) Duan, Y.; Lin, J.-H.;* Xiao, J.-C.*; Gu, Y.-C. Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P). Org. Chem. Front. 2017, 4, 1917-1920.

(18) Duan, Y.; Lin, J.-H.;* Xiao, J.-C.*; Gu, Y.-C. Difluoromethylcarbene for iron-catalyzed cyclopropanation. Chem. Commun. 2017, 53, 3870 - 3873.

(19) Ji, Y.-L.; Luo, J.-J.; Lin, J.-H.;* Xiao, J.-C.*; Gu, Y. C. Cu-Catalyzed C-H Trifluoromethylation of 3-Arylprop-1-ynes for the Selective Construction of Allenic Csp(2)-CF3 and Propargyl Csp(3)-CF3 Bonds. Org. Lett. 2016, 18, 1000-1003.

(20) Duan, Y.; Lin, J.-H.;* Xiao, J.-C.*; Gu, Y. C. A Trifluoromethylcarbene Source. Org. Lett. 2016, 18, 2471-2474.

(21) Deng, Z.; Liu, C.; Zeng, X.-L.; Lin, J.-H.;* Xiao, J.-C.* Nucleophilic 1,1-Difluoroethylation with Fluorinated Phosphonium Salt. J. Org. Chem. 2016, 81, 12084 - 12090.

(22) Ji, Y.-L.; Lin, J.-H.;* Xiao, J.-C.;* Gu, Y.-C. Copper-catalyzed tandem trifluoromethylation/cyclization of internal alkynes. Org. Chem. Front. 2014, 1, 1280-1284.

(23) Lin, J.-H.; Zong, G.; Du, R.-B.; Xiao, J.-C.*; Liu, S. The asymmetric synthesis of CF3- or -CF2-substituted tetrahydroquinolines by employing a chiral phosphoric acid as catalyst. Chem. Commun. 2012, 48, 7738-7740.

(24) Lin, J.-H.; Xiao, J.-C.* The Asymmetric Friedel-Crafts Reaction of Indoles with Fluoroalkylated Nitroalkenes Catalyzed by Chiral Phosphoric Acid. Eur. J. Org. Chem. 2011, 4536-4539.

(25) Lin, J.-H.; Zhang, C.-P.; Zhu, Z.-Q.; Chen, Q.-Y.; Xiao, J.-C.* A novel pyrrolidinium ionic liquid with 1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfonate anion as a recyclable reaction medium and efficient catalyst for Friedel–Crafts alkylations of indoles with nitroalkenes. J. Fluorine Chem. 2009, 130, 394-398.

(26) Lin, J.-H.; Zhang, C.-P.; Xiao, J.-C.* Enantioselective aldol reaction of cyclic ketones with aryl aldehydes catalyzed by a cyclohexanediamine derived salt in the presence of water. Green Chem. 2009, 11, 1750-1753.

（最后更新日期：2024.4.12）